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鐩墠锛屽柈涓€鐨勬按铏曠悊宸ヨ棟鍏锋湁鍤�(y谩n)閲嶇殑灞€闄愭€�锛屼笉鑳芥湁鏁堝湴瑙ｆ焙瑭查寤㈡按娌荤悊鐨勫晱(w猫n)椤�锛屽線寰€闇€瑕佹牴鎿�(j霉)宸ヨ棟鐗规€ч€�(j矛n)琛岄潏娲荤祫鍚堝拰鍎�(y艒u)鍖�锛屾墠鑳藉浜掔浉褰岃(b菙)鎶€琛�(sh霉)缂洪櫡锛屾渶绲傚(sh铆)鐝�(xi脿n)寤㈡按寰挵(hu谩n)鍥炵敤鍜屸€滈浂鎺掓斁鈥�銆傚洜姝わ紝鏍规摎(j霉)铏曠悊宸ヨ棟绲勫悎鐨勮搴﹀拰鍚勮嚜鎶€琛�(sh霉)鐗归粸(di菐n)灏囧叾姝哥磵鐐猴細鍒嗛洟鎶€琛�(sh霉)銆佺敓鐗╂妧琛�(sh霉)鍜岄珮绱�(j铆)姘у寲鎶€琛�(sh霉)銆�

1鍒嗛洟鎶€琛�(sh霉)

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1.1

鑴厷鍜岃捀姘ㄧ祫鍚堝伐钘�

鐩墠鏅亶閲囩敤婧跺姂钀冨彇鑴厷鍜岃捀姘ㄧ祫鍚堝伐钘濆皪(du矛)鐓ゅ寲宸ュ虎姘撮€�(j矛n)琛岄爯(y霉)铏曠悊锛屽洖鏀舵墍鍚湁鐨勯珮婵冨害閰氬拰姘ㄣ€備緥濡�锛屼腑鐓ら緧鍖栧搱鐖炬勘鐓ゅ寲宸ユ湁闄愬叕鍙告敼鑹簡鑴厷宸ヨ棟锛屽(sh铆)鐝�(xi脿n)浜嗚劔閰歌劔姘ㄥ悗pH闄嶅埌鍋忎腑鎬ф按骞�锛屾湁鍒╀簬钀冨彇鑴厷宸ヨ棟鐨勫劒(y艒u)鍖栭亱(y霉n)琛岋紝绡╅伕鐢插熀鐣颁竵鍩洪叜浣滅偤鑴厷钀冨彇鍔�锛岃┎宸ヨ棟灏�(du矛)鍠厓閰氬拰澶氬厓閰氬垎閰嶇郴鏁�(sh霉)鍧囧ぇ浜庝簩鐣颁笝閱氾紝鍙互浣跨附閰氱殑钀冨彇鏁堢巼鎻愰珮鑷�90%浠ヤ笂锛屽嚭姘寸附閰氳唱(zh矛)閲忔績搴﹂檷鑷�400mg/L浠ヤ笅锛屼絾鏄┎宸ヨ棟鍏锋湁鎶€琛�(sh霉)涓嶇┅(w臎n)瀹氭€�锛屽鍔犱簡鏈夋瘨鐗╄唱(zh矛)鎶戝埗鍚庣簩(x霉)鐢熺墿宸ヨ棟鐨勯ⅷ(f膿ng)闅�(xi菐n)銆傚悓鏅�(sh铆)锛岃┎鍏徃閲囩敤钂告皑濉旈€�(j矛n)琛屾按钂告埃姹芥彁-钂告皑宸ヨ棟锛屽皣姘ㄦ爱鍘婚櫎鐜囨彁楂樺埌90%浠ヤ笂銆�

1.2

闄ゆ补鎶€琛�(sh霉)

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1.3

娣峰嚌鍜屽惛闄勬妧琛�(sh霉)

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1.4

鑶滆檿鐞嗘妧琛�(sh霉)

杩戝勾渚�(l谩i)锛岃啘鎶€琛�(sh霉)鍦ㄥ虎姘磋檿鐞嗛牁(l菒ng)鍩熷緱鍒板唬娉涙噳(y墨ng)鐢�锛屽叾涓嚌灏�(du矛)鐓ゅ寲宸ュ虎姘寸殑鐮旂┒鍜屾噳(y墨ng)鐢ㄤ富瑕佹槸鑶滅敓鐗╁弽鎳�(y墨ng)鍣�(MBR)鍜屾烤鑶�銆傞煋瓒呯瓑浠ヨ嚟姘ч爯(y霉)姘у寲鍚庣殑鐓ゆ埃寤㈡按浣滅偤MBR閫�(j矛n)姘�锛屽嚭姘存按璩�(zh矛)閬�(d谩)鍒颁簡鍥炵敤姘寸殑妯�(bi膩o)婧�(zh菙n)銆傚悓鏅�(sh铆)锛屼竴浜涙敼鑹妧琛�(sh霉)淇冮€�(j矛n)浜嗚┎宸ヨ棟鐨勫(sh铆)闅涙噳(y墨ng)鐢�锛屼緥濡係. Y. Jia绛夊湪MBR鍏�(n猫i)鎶曞姞绮夋湯娲绘€х偔鎻愰珮姹℃偿婵冨害铏曠悊鐓ゅ埗姘ｅ虎姘达紝鍙栧緱浜嗛珮鏁堢殑姹℃煋鐗╁幓闄ゆ晥鏋�锛岃€屼笖娲绘€х偔鐨勬姇鍔犳笡灏戜簡璺ㄨ啘澹撳姏锛屾湁鏁堝湴绶╄В浜嗚啘鍫靛銆傚悓鏅�(sh铆)锛岀叅鍖栧伐寤㈡按娣卞害铏曠悊宸ヨ棟鐨勬渶鍚庝竴娈甸€氬父閲囩敤闆欒啘娉�锛屽嵆瓒呮烤绲�(ji茅)鍚堝弽婊查€忓伐钘�锛屽虎姘村彲浠ュ(sh铆)鐝�(xi脿n)60%浠ヤ笂鐨勫洖鐢紝鍓╀綑30%~40%鐨勬績楣芥按閫�(j矛n)鍏ユ績楣芥按绔欑稉(j墨ng)閬�(gu貌)楂樻晥鍙嶆徊閫忕祼(ji茅)鍚堝鏁堣捀鐧�(f膩)宸ヨ棟锛屽虎姘村洖鏀剁巼鍦�95%浠ヤ笂锛屽熀鏈(sh铆)鐝�(xi脿n)寤㈡按鈥滈浂鎺掓斁鈥�銆備絾鏄洐鑶滄妧琛�(sh霉)浠嶈檿鍦ㄥ垵绱�(j铆)鎳�(y墨ng)鐢ㄩ殠娈碉紝鏇村鐨勬槸寮曢€�(j矛n)鍦�(gu贸)澶栫殑鎴愮啛鎶€琛�(sh霉)锛屽瓨鍦ㄨ嚜涓荤爺鐧�(f膩)鐨勬妧琛�(sh霉)闆ｉ鍜岀己涔忓伐绋嬫噳(y墨ng)鐢ㄧ殑缍�(j墨ng)椹�(y脿n)銆�

2鐢熺墿鎶€琛�(sh霉)

闋�(y霉)铏曠悊鍚庣殑鐓ゅ寲宸ュ虎姘村惈鏈夊ぇ閲忕殑鍙敓鐗╅檷瑙ｆ湁姗�(j墨)鐗�锛岄噰鐢ㄧ敓鐗╂妧琛�(sh霉)鏄渶鐐虹稉(j墨ng)婵�(j矛)楂樻晥鐨勮檿鐞嗘柟娉�銆傜劧鑰�锛岀敱浜庤┎寤㈡按涓湁姗�(j墨)鐗╂垚鍒嗗京(f霉)闆滀笖鍏锋湁澶ч噺鏈夋瘨鍜岄洠闄嶈В鐗╄唱(zh矛)锛屼笉鍒╀簬寰敓鐗╃殑鐢熼暦(zh菐ng)锛屼篃闄嶄綆浜嗙敓鐗╁伐钘濆幓闄ゆ薄鏌撶墿鐨勬€ц兘锛屽皫(d菐o)鑷村嚭姘存按璩�(zh矛)闆ｄ互閬�(d谩)鍒板湅(gu贸)瀹舵帓鏀炬(bi膩o)婧�(zh菙n)锛屽皪(du矛)鍙楃磵姘撮珨鐢�(ch菐n)鐢熷毚(y谩n)閲嶅嵄瀹�銆傚洜姝�锛屽ぇ閲忔柊绌庣殑鐢熺墿鏀硅壇宸ヨ棟鍙婂叾绲勫悎琚唬娉涚敤浜庣叅鍖栧伐寤㈡按鐨勭爺绌�锛岀偤鍏垛€滈浂鎺掓斁鈥濈洰妯�(bi膩o)鐨勫(sh铆)鐝�(xi脿n)鎻愪緵浜嗘妧琛�(sh霉)鍜岀悊璜栧熀绀�(ch菙)銆�

2.1

鍘哀鐢熺墿铏曠悊宸ヨ棟

甯歌(gu墨)鐨勫幁姘у伐钘濊檿鐞嗙叅鍖栧伐寤㈡按瀛樺湪鍙嶆噳(y墨ng)鍣ㄥ暉鍕�(d貌ng)鍥伴洠銆佽檿鐞嗘晥鑳戒綆绛夊晱(w猫n)椤�锛屽線寰€渚濊炒浜庢椿鎬х偔鍚搁檮鎴栬€呯█閲嬬殑鏂规硶鎵嶈兘姝ｅ父閬�(y霉n)琛屻€備絾鏄�锛屾椿鎬х偔瀛樺湪鏄撻＝鍜屻€佸啀鐢熷拰鏇存彌鎿嶄綔寰�(f霉)闆滅瓑鍥伴洠锛岃€岀█閲嬬劇(w煤)鐤戝鍔犱簡铏曠悊姘撮噺鍜岄亱(y霉n)琛屾垚鏈�锛屾洿鏈�(hu矛)閫犳垚鏈夋瘨鍜岄洠闄嶈В鐗╄唱(zh矛)鍦ㄥ弽鎳�(y墨ng)鍣ㄥ収(n猫i)鐨勪笉鏂风⿳绱紝璨�(f霉)闈㈠奖闊夸簡鍘哀铏曠悊鏁堟灉銆傝繎浜涘勾鐮旂┒鐧�(f膩)鐝�(xi脿n)锛屽幁姘у井鐢熺墿鍦ㄥ叡浠ｈ瑵鍩鸿唱(zh矛)瀛樺湪姊濅欢涓嬭兘澶犲挤(qi谩ng)鍖栧叾鍒嗚В鏈夋瘨鍜岄洠闄嶈В鏈夋(j墨)鐗╃殑鑳藉姏銆俉. Wang绛夌爺绌朵簡鐢查唶鍏卞熀璩�(zh矛)(鐢查唶500mg/L)鍜岀矇鏈椿鎬х偔(1.0g/L)寮�(qi谩ng)鍖栧幁姘у伐钘濊檿鐞嗙叅鍒舵埃寤㈡按涓厷椤炲寲鍚堢墿鐨勬晥鑳�锛岀祼(ji茅)鏋滆〃鏄庡叐绋檿鐞嗘柟寮忓垎鍒ュ皣閰氶鍖栧悎鐗╃殑鍘婚櫎鐜囩敱30%~40%鎻愰珮鑷�73%鍜�75%宸﹀彸锛岃€屼笖椤憲鏀瑰杽浜嗗虎姘寸殑濂芥哀鐢熷寲鎬ц兘锛岃┎鐮旂┒瑾�(r猫n)鐐虹█閲嬮€�(j矛n)姘存垨鑰呭欢闀�(zh菐ng)鍋滅暀鏅�(sh铆)闁撻洠浠ラ’钁楁彁楂樺幁姘у伐钘濊檿鐞嗙叅鍖栧伐寤㈡按鐨勬晥鏋�銆係. Y. Jia绛夐噰鐢ㄥぇ姣斾緥鍥炴祦鏀硅壇鍘哀宸ヨ棟铏曠悊鐓ゅ寲宸ュ虎姘�锛屾薄鏌撶墿鐨勫幓闄ゆ晥鏋滈’钁楁彁楂�锛屽悓鏅�(sh铆)鍘哀姹℃偿鐨勫井鐢熺墿缇よ惤绲�(ji茅)妲�(g貌u)涔熻鏀硅畩銆傚(sh铆)闅涗笂锛屽幁姘у伐钘濆皪(du矛)COD鍜屾皑姘幓闄よ兘鍔涙湁闄�锛屼絾鏄虎姘寸稉(j墨ng)鍘哀铏曠悊鍚庡舰鎴愬ぇ閲忔槗鐢熺墿闄嶈В鐨勫皬鍒嗗瓙鏈夋(j墨)鐗�锛屽彲浠ラ’钁楁彁楂樺虎姘村彲鐢熷寲鎬у拰濂芥哀闄嶈В鎬�锛岄€欏皪(du矛)浜庣祫鍚堝伐钘濈殑楂樻晥铏曠悊鎬ц兘鍏锋湁鏇撮噸瑕佺殑鎰忕京銆�

2.2

濂芥哀鐢熺墿铏曠悊宸ヨ棟

鐓ゅ寲宸ュ虎姘寸稉(j墨ng)閬�(gu貌)鍘哀铏曠悊鍚庡嚭姘村惈鏈夐珮婵冨害鐨勬薄鏌撶墿鍚屾檪(sh铆)涔熷叿鏈夎純濂界殑鍙敓鍖栨€�锛岄€氬父閲囩敤濂芥哀娲绘€ф薄娉ュ伐钘濋€�(j矛n)涓€姝ヨ檿鐞嗐€傞嚌灏�(du矛)鍌崇当(t菕ng)娲绘€ф薄娉ユ硶铏曠悊鏁堢巼浣庣殑缂洪粸(di菐n)锛屽彲浠ラ€氶亷(gu貌)浜哄伐鎶曞姞鎴栧浐瀹氶Υ鍖栫壒娈婂井鐢熺墿锛岄珮鏁堝幓闄ゅ虎姘翠腑鐗瑰畾鐨勬湁姣掓垨闆ｉ檷瑙ｆ湁姗�(j墨)鐗╋紝鎻愰珮鍘熸湁宸ヨ棟铏曠悊鎬ц兘銆俌. S. Liu绛夊湪涓叅榫嶅寲鍝堢埦婵辩叅鍖栧伐鏈夐檺鍏徃寤㈡按鐢熺墿铏曠悊宸ヨ棟鐝�(xi脿n)鍫�(ch菐ng)浜屾矇姹犵殑搴曟偿涓垎闆㈠嚭4鏍暦(zh菐ng)閺堢兎鐑撮檷瑙ｈ弻锛屽瘜闆嗗煿椁�(y菐ng)鍚庢姇鍔犲埌鐢熺墿绉诲嫊(d貌ng)搴�(MBBR)宸ヨ棟铏曠悊鐓ゅ埗姘ｅ虎姘�锛岄珮鏁堣弻鐨勬姇鍔犵府鐭弽鎳�(y墨ng)鍣ㄥ暉鍕�(d貌ng)鏅�(sh铆)闁�锛屾湁鏁堝湴鎻愰珮浜嗛暦(zh菐ng)閺堢兎鐑村強寤㈡按COD鐨勫幓闄ゆ晥鏋�銆傜洰鍓嶏紝鍝堢埦婵卞伐妤�(y猫)澶у(xu茅)鐨勯煋娲粛鏁欐巿瑾查绲勫凡缍�(j墨ng)灏囧垎闆㈠嚭渚�(l谩i)鐨勯厷闄嶈В鑿屽埗鍌欏嚭鑿屽姂鎶曞姞鑷崇叅鍒舵埃寤㈡按鐢熺墿铏曠悊宸ョ▼锛岄’钁楀湴鎻愰珮浜嗗師宸ヨ棟灏�(du矛)閰氶鐗╄唱(zh矛)鐨勯檷瑙ｆ晥鑳斤紝浣嗘槸锛屽叾闀�(zh菐ng)鏈熻檿鐞嗘晥鏋滀粛闇€閫�(j矛n)涓€姝ョ爺绌�銆傚悓鏅�(sh铆)锛屽ソ姘х敓鐗╄啘閲囩敤鎶曞姞杓夐珨濉枡淇冮€�(j矛n)娲绘€ф薄娉ヤ腑寰敓鐗╁浐钁楃敓闀�(zh菐ng)锛屽叾寰敓鐗╂績搴︽槸鍌崇当(t菕ng)姹℃偿娉曠殑骞惧€�锛屾搧鏈夋洿鐐哄京(f霉)闆滅殑鐢熺墿绯荤当(t菕ng)锛屾洿寮�(qi谩ng)鐨勬姉娌栨搳璨�(f霉)鑽疯兘鍔�锛岄仼鍚堣檿鐞嗗惈鏈夊ぇ閲忔湁姣掑拰闆ｇ敓鐗╅檷瑙ｇ墿璩�(zh矛)鐨勭叅鍒舵埃寤㈡按銆侶.Q. Li绛夐噰鐢∕BBR铏曠悊鐓ゅ埗姘ｅ虎姘�锛屾按鍔涘仠鐣欐檪(sh铆)闁�48h鍚�锛屽嚭姘碈OD銆佺附閰�銆佹皑姘幓闄ょ巼鍒嗗垾閬�(d谩)鍒颁簡81%銆�89%銆�94%锛岃┎鐮旂┒瑾�(r猫n)鐐哄浐钁楃殑鐢熺墿鑶滄瘮鎳告诞娲绘€ф薄娉ュ叿鏈夋洿濂界殑鎶楁矕鎿婅兘鍔涘拰鏈夋(j墨)鐗╅檷瑙ｆ晥鑳�銆傚悓鏅�(sh铆)锛屽ソ姘х敓鐗╄啘宸ヨ棟涓嶅儏鍙互浣滅偤寤㈡按铏曠悊鐨勪簩绱�(j铆)宸ヨ棟锛屼篃甯哥敤浜庡虎姘寸殑娣卞害铏曠悊锛屼腑鐓ら緧鍖栧搱鐖炬勘鐓ゅ寲宸ユ湁闄愬叕鍙搁噰鐢ㄦ洕姘ｇ敓鐗╂烤姹犲皪(du矛)浜岀礆(j铆)铏曠悊鍑烘按閫�(j矛n)琛屾繁搴﹁檿鐞�锛屾渶绲傚嚭姘翠腑COD鍜屾皑姘潎閬�(d谩)鍒板湅(gu贸)瀹舵帓鏀炬(bi膩o)婧�(zh菙n)锛屼笖绯荤当(t菕ng)閬�(y霉n)琛岀┅(w臎n)瀹�銆傚洜姝�锛屽绱�(j铆)濂芥哀鐢熺墿鎶€琛�(sh霉)鍙互閫氶亷(gu貌)鎺у埗婧惰В姘ф績搴︾嚐(y铆ng)閫犲嚭涓嶅悓鐨勫姛鑳藉崁(q奴)鍩熼€�(j矛n)琛屽崝(xi茅)鍚屼綔鐢�锛屼娇鍏跺叿鏈夎壇濂界殑瀵�(sh铆)闅涘伐绋嬫噳(y墨ng)鐢ㄥ児(ji脿)鍊笺€�

3楂樼礆(j铆)姘у寲鎶€琛�(sh霉)

瑭叉妧琛�(sh霉)鏄埄鐢ㄥ寲瀛�(xu茅)鎴栬€呯墿鐞嗘柟娉曞湪娑茬浉鐢�(ch菐n)鐢熷挤(qi谩ng)姘у寲鑷敱鍩�锛屼富瑕佹槸缇ュ熀鑷敱鍩�锛屽皣鏈夋(j墨)鐗╃洿鎺ョう鍖栨垨鑰呰綁(zhu菐n)鍖栫偤灏忓垎瀛愮敘(ch菐n)鐗�锛屽叿鏈夋哀鍖栧竟搴曘€佺劇(w煤)浜屾姹℃煋銆佸仠鐣欐檪(sh铆)闁撶煭銆佹槗浜庡(sh铆)鐝�(xi脿n)鑷嫊(d貌ng)鍖栨搷浣滅瓑鍎�(y艒u)鍕�(sh矛)锛屽湪姘磋檿鐞嗛牁(l菒ng)鍩熻寤ｆ硾鎳�(y墨ng)鐢ㄣ€傝€屼笖锛岃┎鎶€琛�(sh霉)閭勫彲浠ユ湁鏁堝湴鎻愰珮寤㈡按鐨勫彲鐢熷寲鎬�锛屽挤(qi谩ng)鍖栨湁姣掑拰闆ｉ檷瑙ｆ湁姗�(j墨)鐗╃殑鍘婚櫎鏁堣兘锛屾湁鍒╀簬鍚庣簩(x霉)鐢熺墿宸ヨ棟鐨勮檿鐞�锛岃€冩叜鍒扮叅鍖栧伐寤㈡按姘磋唱(zh矛)寰�(f霉)闆溿€佹湁姗�(j墨)鐗╂績搴﹂珮銆佷笉鍒╀簬姘у寲閬�(gu貌)绋嬮€�(j矛n)琛屼互鍙婅檿鐞嗘垚鏈亷(gu貌)楂樼瓑鍟�(w猫n)椤岋紝瑭叉妧琛�(sh霉)寰€寰€鐢ㄤ簬娣卞害铏曠悊宸ヨ棟銆傜洰鍓嶏紝澶氱ó楂樼礆(j铆)姘у寲鎶€琛�(sh霉)鍦ㄧ叅鍖栧伐寤㈡按铏曠悊閬�(gu貌)绋嬩腑琚唬娉涚殑鐮旂┒锛屽叾涓璅enton姘у寲鍜岃嚟姘ч珮绱�(j铆)姘у寲鍥犲叾鎿嶄綔绨�(ji菐n)鍠�銆佸弽鎳�(y墨ng)婧拰銆佹哀鍖栬兘鍔涘挤(qi谩ng)鎴愮偤鐮旂┒鐨勭啽榛�(di菐n)鍜屾噳(y墨ng)鐢ㄧ殑閲嶉粸(di菐n)銆�

3.1

Fenton姘у寲鎶€琛�(sh霉)

Fenton姘у寲鐨勫師鐞嗘槸Fe2+浣滅偤閬�(gu貌)姘у寲姘殑鍌寲鍔戯紝鍦ㄩ吀鎬ф浠朵笅(pH鐐�2~4)锛岀敘(ch菐n)鐢熺茎鍩鸿嚜鐢卞熀绛夋哀鍖栧熀鍦�(tu谩n)灏�(du矛)姘翠腑姹℃煋鐗╅€�(j矛n)琛屾哀鍖栭檷瑙�銆傝┎鎶€琛�(sh霉)鍏锋湁瑷�(sh猫)鍌欑啊(ji菐n)鍠�銆佹妧琛�(sh霉)闈堟椿涓旈珮鏁堝粔鍍�(ji脿)绛夌壒榛�(di菐n)锛屾槸杓冪偤甯歌(ji脿n)鐨勯珮绱�(j铆)姘у寲鎶€琛�(sh霉)銆傚嫉瀚诲绛夐噰鐢‵enton宸ヨ棟灏�(du矛)鐒﹀寲寤㈡按閫�(j矛n)琛岄爯(y霉)铏曠悊瑭﹂(y脿n)锛屽湪鏈€浣宠│椹�(y脿n)姊濅欢涓�锛岃┎鎶€琛�(sh霉)灏�(du矛)寤㈡按COD鍜岄厷鐨勫幓闄ょ巼鍒嗗垾閬�(d谩)鍒�88.1%鍜�89.5%銆傝稒鏇変寒绛夎€冨療浜咶enton姘у寲鎶€琛�(sh霉)娣卞害铏曠悊鐒﹀寲寤㈡按鐨勬晥鏋�锛岀祼(ji茅)鏋滆〃鏄庡嚭姘磋壊搴﹀拰COD鍧囨豢瓒冲湅(gu贸)瀹剁挵(hu谩n)淇濊姹�銆傚悓鏅�(sh铆)锛孎(xi脿n)enton姘у寲鎶€琛�(sh霉)鑸囧叾浠栨妧琛�(sh霉)鑱�(li谩n)鍚堜娇鐢�锛屽寰尝銆佹贩鍑濈瓑锛屽彲閬�(d谩)鍒版彁楂樿檿鐞嗘晥鏋滃拰闄嶄綆鑳借€楃殑鐩殑銆傛湵鍑屽嘲绛夐噰鐢ㄥ井娉㈡浠朵笅鐨凢enton鏂规硶铏曠悊鍚厷寤㈡按锛屽虎姘碈OD鍜屾彯鐧�(f膩)閰氬幓闄ょ巼鍒嗗垾瓒呴亷(gu貌)81%鍜�99%銆備絾鏄紝鍌崇当(t菕ng)鐨凢enton鎶€琛�(sh霉)瀛樺湪閬�(gu貌)姘у寲姘埄鐢ㄧ巼浣�銆侀仼鐢╬H鑼冨湇鐙圭獎鍜屽嚭姘翠腑鍚珮婵冨害閻甸洟瀛愪互鍙婄敘(ch菐n)鐢熷惈閻垫薄娉ユ薄鏌撶瓑鍟�(w猫n)椤岋紝鍤�(y谩n)閲嶉檺鍒惰┎鎶€琛�(sh霉)寤ｆ硾浣跨敤銆傚洜姝�锛岃ū澶欶enton鐨勬敼鑹妧琛�(sh霉)琚繁鍏ョ爺绌�锛屼緥濡傚厜-Fenton銆侀浕-Fenton銆侀潪鍧囩浉Fenton绛�銆傞櫝绌庢晱绛夋噳(y墨ng)鐢ㄤ笁缍浕妤�-闆籉enton瑭﹀姂娉曡檿鐞嗗惈閰氬虎姘�锛屽熀浜庨浕瑙ｉ亷(gu貌)绋嬩腑鐢�(ch菐n)鐢熺殑缇ュ熀鑷敱鍩虹殑寮�(qi谩ng)姘у寲鑳藉姏锛屽皣寤㈡按涓厷闆昏В鐩磋嚦瀹屽叏鍘婚櫎銆傝€屽厜-Fenton绯荤当(t菕ng)涓厜鐨勫偝璩�(zh矛)瀹规槗鍙楀埌姘翠腑鑹插害鍜屾嚫娴墿鐨勫奖闊�锛屽伐妤�(y猫)鎳�(y墨ng)鐢ㄩ渶瑕侀爯(y霉)鍏堝幓闄よ壊搴︾瓑骞叉摼鍥犲瓙锛屼笉鍒╀簬鍏跺湪鐓ゅ寲宸ュ虎姘寸殑宸ョ▼鎳�(y墨ng)鐢�銆傞潪鍧囩浉Fenton鏄€氶亷(gu貌)Fe3+璨�(f霉)杓変簬杓夐珨涓�锛屼綔鐐哄偓鍖栧姂鎻愰珮閬�(gu貌)姘у寲姘敘(ch菐n)鐢熻嚜鐢卞熀鐨勬暩(sh霉)閲�锛屽挤(qi谩ng)鍖栧皪(du矛)寤㈡按姹℃煋鐗╃殑鍘婚櫎鏁堣兘锛岃┎鍌寲鍔戞槗浜庡埗鍌欏拰鍒嗛洟锛岀敓鐗╁吋瀹规€уソ锛屼笉闇€瑕佸毚(y谩n)鏍兼帶鍒秔H锛屽彲閲嶅京(f霉)鍥炴敹浣跨敤锛岀稉(j墨ng)婵�(j矛)楂樻晥涓斾笉瀛樺湪浜屾姹℃煋銆傚叾鍌寲鍔戣級楂斾竴鑸槸澶氬瓟鐨勫浐楂�锛屼緥濡傛椿鎬х偔銆佹椿鎬х偔绾栫董銆佹哺鐭�銆佹ü(sh霉)鑴傜瓑锛屽埄鐢ㄥ惛闄勫拰鍌寲鍗�(xi茅)鍚屼綔鐢ㄨ檿鐞嗗虎姘翠腑姹℃煋鐗�銆�

W. Wang绛夊皣绱嶇背绱�(j铆)鐨凢e3O4璨�(f霉)杓変簬姘村嚌鑶�锛岄€氶亷(gu貌)鎺у埗pH鎺㈤嚌瑾�(di脿o)绡€(ji茅)Fe3O4鐨勯噵鏀�锛屽偓鍖栭亷(gu貌)姘у寲姘檿鐞嗘按涓厷椤炵墿璩�(zh矛)锛屽彇寰椾簡楂樻晥鐨勬哀鍖栨晥鏋�锛岃€屼笖鍌寲鍔戝叿鏈夐暦(zh菐ng)鏈熷偓鍖栨椿鎬�銆傜劧鑰�锛岃ū澶氶珮鏁堢殑闈炲潎鐩窮enton鍌寲鍔戦兘鍏锋湁鍒跺倷宸ヨ棟寰�(f霉)闆�銆佺敓鐢�(ch菐n)璨�(f猫i)鐢ㄥ亸楂樼殑缂洪櫡锛屽緢闆ｉ€�(j矛n)琛屽伐妤�(y猫)鍖栫殑鎳�(y墨ng)鐢�銆傚洜姝�锛屾湁瀛�(xu茅)鑰呴噰鐢ㄤ綆鎴愭湰鐨勫虎姘寸敓鐗╄檿鐞嗗伐钘濆墿浣欐薄娉ュ埗鍌欐椿鎬х偔璨�(f霉)杓夐噾灞哀鍖栫墿浣滅偤闈炲潎鐩窮enton鐨勫偓鍖栧姂锛屽彇寰椾簡鑹ソ鐨勮檿鐞嗘晥鏋�锛岃┎鐮旂┒瑾�(r猫n)鐐哄偓鍖栨(j墨)鐞嗘槸鐢变簬姹℃偿涓瓨鍦ㄥ绋殑閲戝爆姘у寲鐗╃殑鍗�(xi茅)鍔╀綔鐢�銆傜洰鍓�锛岄€欓瀵�(sh铆)鐢ㄥ瀷鍌寲鍔戠殑鐮旂┒涓昏闆嗕腑浜庢按涓磾鐗╄唱(zh矛)鐨凢enton姘у寲锛屽皪(du矛)鐓ゅ埗姘ｅ虎姘寸殑铏曠悊鏁堟灉灏氭湭瑕�(ji脿n)鍫�(b脿o)閬�锛屽彲浠ラ爯(y霉)瑕�(ji脿n)鎬ц兘楂樻晥銆佸児(ji脿)鏍间綆寤変笖鍒跺倷绨�(ji菐n)鍠殑鍌寲鍔戠爺鍒跺皣鏈�(hu矛)鏄┎鎶€琛�(sh霉)鎶曞叆宸ョ▼鎳�(y墨ng)鐢ㄧ殑闂�(gu膩n)閸�銆�

3.2

鑷哀楂樼礆(j铆)姘у寲鎶€琛�(sh霉)

瑭叉妧琛�(sh霉)鏄湪鑷哀姘у寲閬�(gu貌)绋嬩腑鍒╃敤婧舵恫鍫挎€�(pH>5)銆侀噾灞洟瀛�銆佸浐鎱�(t脿i)閲戝爆銆侀噾灞哀鍖栫墿鎴栬矤(f霉)杓夊湪杓夐珨涓婇噾灞垨閲戝爆姘у寲鐗╀互鍙婄う鐗╄唱(zh矛)绛変績閫�(j矛n)鑷哀鍒嗗瓙鐨勫垎瑙�锛屼互鐢�(ch菐n)鐢熸洿澶氬挤(qi谩ng)姘у寲鎬х殑鑷敱鍩�锛屾彁楂樿嚟姘ф哀鍖栨湁姗�(j墨)鐗╃殑鎬ц兘銆傞洊鐒跺牽鎬х挵(hu谩n)澧冨埄浜庤嚟姘х敘(ch菐n)鐢熺茎鍩鸿嚜鐢卞熀锛屼絾鏄痯H灏�(du矛)鑷哀鍖栨€ц兘鐨勫奖闊垮京(f霉)闆�锛岄珮鍫挎€х挵(hu谩n)澧冩湁鍙兘瀛樺湪纰抽吀鏍规垨閲嶇⒊閰告牴鎹曠嵅缇ュ熀鑷敱鍩�锛屽緸鑰屾姂鍒舵垨涓柗閺�?zh菙n)绐栬陡顕；?y墨ng)銆傚湪鍚岀瓑姊濅欢涓�锛岀茎鍩鸿嚜鐢卞熀鐨勯潪閬告搰鎬у彲鑳芥渻(hu矛)闄嶄綆楂旂郴灏�(du矛)鏌愪簺鐗瑰緛姹℃煋鐗╃殑鍘婚櫎鏁堢巼锛屽牽鎬ф浠朵笅鑷哀鍖栧惈閰氬虎姘碈OD鐨勫幓闄ょ巼鏇撮珮锛屼絾閰告€ф浠跺皪(du矛)鍏堕檷瑙ｉ厷椤炲寲鍚堢墿娌�(m茅i)鏈夐’钁楀奖闊�銆傚彟涓€鏂归潰锛岃ū澶氱祫鍚堝伐钘濆彲浠ュ寮�(qi谩ng)鑷哀姘у寲鑳藉姏锛屽妷閲戞硥绛夐噰鐢℉2O2/O3鍜孶V/O3娣卞害铏曠悊鐒﹀寲寤㈡按锛岀浉灏�(du矛)浜庡柈鐛�(d煤)鑷哀姘у寲锛屽叐绋祫鍚堝伐钘濆皪(du矛)COD鍘婚櫎鐜囧潎鏈変竴瀹氱▼搴︾殑鎻愰珮锛屼絾鏄�锛孒2O2/O3绯荤当(t菕ng)鐨勮檿鐞嗘晥鏋滃彇姹轰簬H2O2鐨勬姇鍔犻噺锛屽急鍖栦簡鑷哀鐨勬哀鍖栦綔鐢紝绱绶氬偝鎾槗鍙楁按涓壊搴︾殑骞叉摼锛岀己灏戝(sh铆)鐢ㄦ€�銆傚偓鍖栬嚟姘ф哀鍖栨妧琛�(sh霉)閫氶亷(gu貌)鍌寲鍔戠殑浣跨敤鍏嬫湇浜嗗偝绲�(t菕ng)鑷哀鐨勭己闄凤紝鍏锋湁妤靛挤(qi谩ng)鐨勬哀鍖栬兘鍔�锛屽彲浠ュ畬鍏ㄥ湴绀﹀寲鏈夋(j墨)鐗╋紝涓斾笉鏈�(hu矛)鐢�(ch菐n)鐢熶簩娆℃薄鏌撶瓑鍟�(w猫n)椤�锛屾垚鐐轰簡鐮旂┒鐨勭啽榛�(di菐n)闋�(l菒ng)鍩�锛屼篃鏇撮仼鐢ㄤ簬寤㈡按铏曠悊鐨勫伐绋嬪寲鎳�(y墨ng)鐢�銆傞嚌灏�(du矛)鍌寲鍔戝湪姘翠腑瀛樺湪褰㈠紡锛屽皣鍏跺垎鐐哄潎鐩稿偓鍖栧拰闈炲潎鐩稿偓鍖栬嚟姘ф哀鍖栨妧琛�(sh霉)銆傚父鐢ㄥ埌鐨勫潎鐩稿偓鍖栧姂涓€鑸偤閬�(gu貌)娓￠噾灞洟瀛怓e2+銆丮n2+銆丯i2+銆丆o2+銆丆d2+銆丆u2+銆丄g+銆丆r3+绛�銆傝┎鎶€琛�(sh霉)鐨勫彲鑳芥(j墨)鐞嗘槸閬�(gu貌)娓￠噾灞洟瀛愪績閫�(j矛n)鑷哀鍒嗚В鐢�(ch菐n)鐢熺茎鍩鸿嚜鐢卞熀鎴栬€呰垏鏈夋(j墨)鐗╁垎瀛愬舰鎴愭洿鏄撳弮鑸囧弽鎳�(y墨ng)鐨勭怠(lu貌)鍚堢墿寰炶€岃鑷哀鍒嗗瓙鐩存帴姘у寲銆傜劧鑰�锛屽偓鍖栧姂鏄撴祦澶卞拰寮曞叆閲戝爆闆㈠瓙姹℃煋绛夊晱(w猫n)椤岄檺鍒跺叾鍦ㄦ按铏曠悊宸ョ▼涓殑鎳�(y墨ng)鐢ㄣ€傚悓鏅�(sh铆)锛岄潪鍧囩浉鍌寲鑷哀鍖栨妧琛�(sh霉)鏄€氶亷(gu貌)鍥洪珨鍌寲鍔戜締(l谩i)鎻愰珮鑷哀姘у寲姘翠腑姹℃煋鐗╃殑鎬ц兘锛屽偓鍖栧姂鏄撲簬鍒嗛洟锛屼笉鏈�(hu矛)鐢�(ch菐n)鐢熶簩娆℃薄鏌�锛屾洿鐐洪仼鐢ㄤ簬鐓ゅ埗姘ｅ虎姘寸殑娣卞害铏曠悊銆傞煋娲粛绛夐€氶亷(gu貌)璨�(f霉)杓夐亷(gu貌)娓￠噾灞妳鍜岄尦鐨勬椿鎬х偔浣滅偤鍌寲鍔戞彁楂樿嚟姘ч檷瑙ｇ叅鍖栧伐寤㈡按姹℃煋鐗╂€ц兘锛岀祼(ji茅)鏋滆〃鏄庤檿鐞嗗悗鍑烘按COD鍜屾皑姘仈(d谩)鍒板煄閹�(zh猫n)姹℃按铏曠悊寤犳薄鏌撶墿鎺掓斁涓€绱�(j铆)B妯�(bi膩o)婧�(zh菙n)锛屽虎姘村彲鐢熷寲鎬ф槑椤彁楂�銆傜劧鑰�锛屽偓鍖栧姂鐨勬椿鎬ф槗鍙楁按璩�(zh矛)鍜屽弽鎳�(y墨ng)姊濅欢绛夊洜绱犵殑褰遍熆锛岀敋鑷冲悓涓€绋偓鍖栧姂鍦ㄨ檿鐞嗕笉鍚岄鍨嬪虎姘存檪(sh铆)涔熸渻(hu矛)鍏锋湁涓嶅悓鐨勮檿鐞嗚兘鍔�銆傚洜姝�锛屽(sh铆)闅涘伐绋嬩腑闂�(gu膩n)浜庨潪鍧囩浉鑷哀鍌寲鎶€琛�(sh霉)鎳�(y墨ng)鐢ㄧ殑鍫�(b脿o)閬撹純灏�锛岀爺鐧�(f膩)浣庢垚鏈拰楂樻晥鎬ц兘鐨勫偓鍖栧姂鏄┎鎶€琛�(sh霉)鑳藉宸ョ▼鍖栨噳(y墨ng)鐢ㄧ殑闂�(gu膩n)閸�銆�

3.3

闆诲寲瀛�(xu茅)鍌寲姘у寲鎶€琛�(sh霉)

瑭叉妧琛�(sh霉)鏄€氶亷(gu貌)鍏锋湁鍌寲鎬ц兘鐨勯噾灞哀鍖栫墿闆绘サ锛岀敘(ch菐n)鐢熷叿鏈夊挤(qi谩ng)姘у寲鑳藉姏鐨勭茎鍩鸿嚜鐢卞熀鎴栧叾浠栬嚜鐢卞熀鏀绘搳婧舵恫涓殑鏈夋(j墨)姹℃煋鐗╋紝浣垮叾瀹屽叏鍒嗚В鐐虹劇(w煤)瀹崇殑H2O鍜孋O2銆傚憘璨磋姮绛夐€氶亷(gu貌)姘ｅ嚌鑶犵矑瀛愰浕妤佃檿鐞嗚嫰閰氬虎姘达紝COD鍘婚櫎鐜囨渶楂樺彲閬�(d谩)97.5%锛屽惊鐠�(hu谩n)50娆″悗锛屽叾灏�(du矛)COD鍘婚櫎鐜囦粛鍦�80%浠ヤ笂銆俋. Zhu绛夐噰鐢ㄧ〖鎽婚洔閲戝墰鐭抽浕妤甸浕鍖栧(xu茅)姘у寲鐒﹀寲寤㈡按鐢熷寲鍑烘按锛岀煭鏅�(sh铆)闁撳収(n猫i)姘翠腑鏈夋(j墨)鐗╁畬鍏ㄧう鍖栵紝鎬ц兘濂戒簬SnO2鍜孭bO2闆绘サ銆傜洰鍓�锛岃┎鎶€琛�(sh霉)鐨勭爺绌跺闆嗕腑鍦ㄩ浕鍌寲姗�(j墨)鐞嗙殑鐮旂┒銆侀浕妤垫潗鏂欑殑闁�(k膩i)鐧�(f膩)鐮斿埗锛岃ō(sh猫)瑷�(j矛)鍑洪珮鏁堝悎鐞嗙殑鍙嶆噳(y墨ng)鍣�锛屽欢闀�(zh菐ng)闆绘サ鐨勪娇鐢ㄥ＝鍛戒篃鏄皣鍏跺伐妤�(y猫)鍖栨噳(y墨ng)鐢ㄦ墍蹇呴爤瑙ｆ焙鐨勫晱(w猫n)椤�銆�

3.4

婵曞紡姘у寲娉�

瑭叉妧琛�(sh霉)鏄湪楂樻韩(150~350 鈩�)銆侀珮澹�(5~20MPa)姊濅欢涓�锛屽埄鐢ㄦ哀姘ｆ垨绌烘埃浣滅偤姘у寲鍔�锛屾哀鍖栨按涓憾瑙ｆ厠(t脿i)鎴栨嚫娴厠(t脿i)鐨勬湁姗�(j墨)鐗╂垨閭勫師鎱�(t脿i)鐒�(w煤)姗�(j墨)鐗╃殑姘磋檿鐞嗘妧琛�(sh霉)锛屽叿鏈夎檿鐞嗘晥鐜囬珮锛屼笉鏄撶敘(ch菐n)鐢熶簩娆℃薄鏌撶殑鍎�(y艒u)鍕�(sh矛)锛屼絾涔熷瓨鍦ㄨ檿鐞嗘垚鏈珮銆佽ō(sh猫)鍌欒姹傞珮鍜屾姇璩囬珮绛夌己闄凤紝寰€寰€鍙綔鐐洪珮婵冨害鏈夋瘨鍜岄洠闄嶈В鐗╄唱(zh矛)鐨勫伐妤�(y猫)寤㈡按闋�(y霉)铏曠悊鎶€琛�(sh霉)锛岃┎鎶€琛�(sh霉)鑳藉闄嶄綆寤㈡按COD鍜屾彁楂樺叾鍙敓鍖栨€�锛岀劧鍚庡啀鐢ㄥ悗绾�(x霉)鐢熺墿娉曡檿鐞�锛岄檷浣庤兘鑰�銆傚攼鍙楀嵃绛夐噰鐢ㄨ┎鎶€琛�(sh霉)铏曠悊楂樻績搴﹀惈閰氬虎姘�锛屽湪姘у垎澹撳拰婧害鍒嗗垾鐐�0.7~5 MPa鍜�150~250 鈩冩檪(sh铆)锛岄厷鍒嗚В鐜囩偤86%~99%銆傞櫝鎿佽粛绛夊湪婵曞紡姘у寲鑻厷寤㈡按閬�(gu貌)绋嬩腑鎶曞姞娲绘€х偔浣滅偤鍌寲鍔�锛屽急鍖栦簡婧害灏�(du矛)瑭叉妧琛�(sh霉)鐨勯檺鍒躲€�

3.5

瓒呰嚚鐣屾按姘у寲娉�

瓒呰嚚鐣屾按姘у寲鐨勫師鐞嗘槸鍦ㄩ珮婧�(>374 鈩�)銆侀珮澹�(>22.1MPa)鐠�(hu谩n)澧冧笅锛屽皣浣滅偤婧跺姂鐨勬按铏曚簬瓒呰嚚鐣岀媭鎱�(t脿i)锛屼互姘у垎瀛愪綔鐐烘哀鍖栧姂姘у寲姘翠腑鏈夋(j墨)鐗╃殑鏂规硶銆俌. Wang绛夐噰鐢∕n2O3銆丆o2O3鍜孋uO浣滅偤鍌寲鍔戞彁楂樿秴鑷ㄧ晫姘存哀鍖栫叅鍒舵埃寤㈡按鐨勬晥鑳�锛岀祼(ji茅)鏋滆〃鏄庯紝鍦ㄦ韩搴︾偤380~460鈩�锛屾哀姘ｆ瘮鐜囩偤1.5~3.5姊濅欢涓嬶紝铏曠悊鍚庡嚭姘撮仈(d谩)鍒板湅(gu贸)瀹跺煄閹�(zh猫n)姹℃按鎺掓斁涓€绱�(j铆)A妯�(bi膩o)婧�(zh菙n)锛屽叾涓瑿o2O3鐨勫偓鍖栨椿鎬ф渶寮�(qi谩ng)锛岄噾灞洟瀛愭瀽鍑鸿純灏�銆�

4绲�(ji茅)璜�

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(渚�(l谩i)婧愶細銆婂伐妤�(y猫)姘磋檿鐞嗐€嬮洔蹇�, 2017骞寸1鏈�锛屽弮鑰冩枃鐛�(xi脿n)鐣�)